MATERIALS ENGINEERING

New video showing the atom-by-atom growth of carbon nanotubes reveals they rotate as they grow, much like the halting motion of a mechanical clock's second hand.

Published online this month in the American Chemical Society's journal Nano Letters by researchers at France's Université Lyon1/CNRS and Houston's Rice University, the research provides the first experimental evidence of how individual carbon atoms are added to growing nanotubes.

"The key issue for realizing the potential of carbon nanotubes has always been better control of their growth," said team lead Stephen Purcell of the Université Lyon1/CNRS. "Our findings offer new insights for better measurement, modeling and control of nanotube growth."

Carbon nanotubes are long, hollow cylinders of pure carbon. They are hair-like in shape but are about 100,000 times smaller than human hair. They are also about six times stronger than steel, conduct electricity as well as copper and are almost impervious to radiation and chemical destruction. As a result, scientists are keen to use them in superstrong, "smart" materials, but they need to better understand how to produce them.

"The images from Dr. Purcell's lab show the atom-by-atom 'self assembly' of a nanotube," said Rice co-author Boris Yakobson, professor in mechanical engineering and materials science and of chemistry. "The video offers compelling evidence of the rotational motion that accompanies nanotube growth. It brings to mind Galileo's famous quote, 'And yet, it does turn.'"

In February, Yakobson offered a new theory suggesting that nanotubes grow like tiny, woven tapestries, with new atoms attaching to twisting atomic threads. The new video appears to support the theory, indicating that atoms are added in pairs as the tube spins and grows.

To create the images, Purcell's team at LPMCN (Laboratoire de Physique de la Matière Condensée et Nanostructures) used a field emission microscope (FEM). A few atoms of metal catalyst were placed on the tip of the FEM's needle-like probe, and carbon nanotubes grew atop the metal catalyst. An electric current was passed lengthwise through the probe and nanotube, and it projected a bright, top-down image of the nanotube onto a phosphor screen. The bright spot was filmed by a video camera, which revealed the nanotube's rotation during growth.

In one case, a nanotube turned approximately 180 times during its 11-minute growth. A frame-by-frame analysis of the video showed that the rotation proceeded in discrete steps -- much like the halting motion of the second hand on a mechanical clock -- with about 24 steps per rotation.

"The results support our predictions of how nanotubes grow," Yakobson said. "The video shows rotational movement during growth, as carbon atoms are added in pairs to the twisting, chiral network of carbon atoms that comprise the nanotube."

Co-authors include Mickaël Marchand, Catherine Journet, Dominique Guillot and Jean-Michel Benoit, all of Université Lyon. The research was supported by the Programme en Nanosciences et Nanotechnologies of France's L'Agence Nationale de Recherche, the National Science Foundation and the Air Force Research Laboratory.

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Journal reference:

1. Mickaël Marchand, Catherine Journet, Dominique Guillot, Jean-Michel Benoit, Boris I. Yakobson, Stephen T. Purcell. Growing a Carbon Nanotube Atom by Atom: 'And Yet It Does Turn'. Nano Letters, 2009; DOI: 10.1021/nl901380u

The description of compounds and interactions between atoms is one of the basic objectives of chemistry. Admittedly, chemical bonding models, which describe these properties very well, already exist. However, any deviation from the normal factors may lead to improving the models further. Chemists with Professor Thomas M. Klapötke at Ludwig-Maximilians-Universität (LMU) München have now analyzed a molecule, which has an extremely short bond length.

As reported by the researchers in Nature Chemistry, the carbon atom and the chlorine atom in the so-called chlorotrinitromethane molecule are only 1.69 Angstroms apart from one another. "Non-covalent interactions are one of the factors responsible for this short distance", declared Göbel, whose doctoral thesis revealed the new results. "A better understanding of these interactions is important and useful in all areas, where molecular recognition and self-assembly come into play."

Chemical bond models that have been successfully used for well over a century assume that a good description of the properties of a compound can be obtained while ignoring all but the nearest-neighbour bonding interactions. The idea that electrostatic interactions between second, third and even further neighbors are important and should not be ignored has not been a common notion so far. The team of Professor Thomas M. Klapötke of the Department of Chemistry and Biochemistry at LMU Munich, primarily concerned with the synthesis and investigation of new high-energy materials, has now demonstrated for the first time that even second and third neighbors can have a decisive effect on the properties of a chemical bond.

For their investigation, the researchers chose the so-called chlorotrinitromethane molecule, a compound, consisting of the halogen chlorine and the pseudohalogen trinitromethyl group. The latter is composed of one carbon atom and three nitro groups. The trinitromethyl unit belongs to the group of pseudohalogens, which has properties similar to those of the halogens. Both groups are composed of non-metals, which are generally present in the gaseous or liquid state and form salts with metals. Contrary to the halogens, however, the pseudohalogens, instead of being true chemical elements, are chemical groups composed of different elements.

Using X-ray structural analysis, the researchers succeeded for the first time in revealing the internal structure of the chlorotrinitromethane molecule and drawing conclusions concerning the distances between the individual atoms. In their analyses, the chemists came up against a particularly interesting property of the chlorotrinitromethane molecule, namely the distance between its chlorine atom and its carbon atom is only 1.69 Angstroms. An Angstrom is 10-7 millimeters. The distance, now detected between the atoms, is the shortest distance ever observed for comparable chlorine-carbon single bonds. All previously measured distances fall within the range of approximately 1.71 and 1.91 Angstroms.

By means of theoretical calculations, carried out in cooperation with Professor Peter Politzer and Dr. Jane S. Murray of the University of New Orleans in the USA, the researchers were able to reproduce the distribution of electrical charges within the molecule. It turned out that the chlorine atom has a completely positive electrostatic potential, a rare case, since chlorine usually has a negative electrostatic potential in other molecules. Together with the charge distributions of the remaining atoms, this finding explains why the chlorine and carbon atoms are linked so tightly to one another. The results impressively show that electrostatic interactions between atoms within a molecule can have a significant effect on bond lengths, even if these atoms are not linked directly to one of the two atoms that form the bond.

In the case of chlorotrinitromethane, this effect is particularly pronounced and leads to an unusually short chlorine-carbon bond. However, it could be of importance in various other cases, especially in areas, where molecules recognize one another and assemble to larger structures. These mechanisms play an important role, for example, in biological systems and in nanotechnology.

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Journal reference:

1. Göbel et al. Chlorotrinitromethane and its exceptionally short carbon-chlorine bond. Nature Chemistry, 2009; DOI: 10.1038/nchem.179

The ability to create tiny patterns is essential to the fabrication of computer chips and many other current and potential applications of nanotechnology. Yet, creating ever smaller features, through a widely-used process called photolithography, has required the use of ultraviolet light, which is difficult and expensive to work with.

John Fourkas, Professor of Chemistry and Biochemistry in the University of Maryland College of Chemical and Life Sciences, and his research group have developed a new, table-top technique called RAPID (Resolution Augmentation through Photo-Induced Deactivation) lithography that makes it possible to create small features without the use of ultraviolet light.

Photolithography uses light to deposit or remove material and create patterns on a surface. There is usually a direct relationship between the wavelength of light used and the feature size created. Therefore, nanofabrication has depended on short wavelength ultraviolet light to generate ever smaller features.

"The RAPID lithography technique we have developed enables us to create patterns twenty times smaller than the wavelength of light employed,"explains Dr. Fourkas, "which means that it streamlines the nanofabrication process. We expect RAPID to find many applications in areas such as electronics, optics, and biomedical devices."

"If you have gotten a filling at the dentist in recent years,"says Fourkas, "you have seen that a viscous liquid is squirted into the cavity and a blue light is then used to harden it. A similar process of hardening using light is the first element of RAPID. Now imagine that your dentist could use a second light source to sculpt the filling by preventing it from hardening in certain places. We have developed a way of using a second light source to perform this sculpting, and it allows us to create features that are 2500 times smaller than the width of a human hair."

Both of the laser light sources used by Fourkas and his team were of the same color, the only difference being that the laser used to harden the material produced short bursts of light while the laser used to prevent hardening was on constantly. The second laser beam also passed through a special optic that allowed for sculpting of the hardened features in the desired shape.

"The fact that one laser is on constantly in RAPID makes this technique particularly easy to implement,"says Fourkas, "because there is no need to control the timing between two different pulsed lasers."

Fourkas and his team are currently working on improvements to RAPID lithography that they believe will make it possible to create features that are half of the size of the ones they have demonstrated to date.

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Journal reference:

1. Linjie Li, Rafael R. Gattass, Erez Gershgorem, Hana Hwang and John T. Fourkas. Achieving lambda/20 Resolution by One-Color Initiation and Deactivation of Polymerization. Science, April 10, 2009

The design of efficient systems for splitting water into hydrogen and oxygen, driven by sunlight is among the most important challenges facing science today, underpinning the long term potential of hydrogen as a clean, sustainable fuel. But man-made systems that exist today are very inefficient and often require additional use of sacrificial chemical agents. In this context, it is important to establish new mechanisms by which water splitting can take place.

Now, a unique approach developed by Prof. David Milstein and colleagues of the Weizmann Institute’s Organic Chemistry Department, provides important steps in overcoming this challenge. During this work, the team demonstrated a new mode of bond generation between oxygen atoms and even defined the mechanism by which it takes place. In fact, it is the generation of oxygen gas by the formation of a bond between two oxygen atoms originating from water molecules that proves to be the bottleneck in the water splitting process. Their results have recently been published in Science.

Nature, by taking a different path, has evolved a very efficient process: photosynthesis – carried out by plants – the source of all oxygen on Earth. Although there has been significant progress towards the understanding of photosynthesis, just how this system functions remains unclear; vast worldwide efforts have been devoted to the development of artificial photosynthetic systems based on metal complexes that serve as catalysts, with little success. (A catalyst is a substance that is able to increase the rate of a chemical reaction without getting used up.)

The new approach that the Weizmann team has recently devised is divided into a sequence of reactions, which leads to the liberation of hydrogen and oxygen in consecutive thermal- and light-driven steps, mediated by a unique ingredient – a special metal complex that Milstein’s team designed in previous studies. Moreover, the one that they designed – a metal complex of the element ruthenium – is a ‘smart’ complex in which the metal center and the organic part attached to it cooperate in the cleavage of the water molecule.

The team found that upon mixing this complex with water the bonds between the hydrogen and oxygen atoms break, with one hydrogen atom ending up binding to its organic part, while the remaining hydrogen and oxygen atoms (OH group) bind to its metal center.

This modified version of the complex provides the basis for the next stage of the process: the ‘heat stage.’ When the water solution is heated to 100 degrees C, hydrogen gas is released from the complex – a potential source of clean fuel – and another OH group is added to the metal center.

‘But the most interesting part is the third ‘light stage,’’ says Milstein. ‘When we exposed this third complex to light at room temperature, not only was oxygen gas produced, but the metal complex also reverted back to its original state, which could be recycled for use in further reactions.’

These results are even more remarkable considering that the generation of a bond between two oxygen atoms promoted by a man-made metal complex is a very rare event, and it has been unclear how it can take place. Yet Milstein and his team have also succeeded in identifying an unprecedented mechanism for such a process. Additional experiments have indicated that during the third stage, light provides the energy required to cause the two OH groups to get together to form hydrogen peroxide (H2O2), which quickly breaks up into oxygen and water. ‘Because hydrogen peroxide is considered a relatively unstable molecule, scientists have always disregarded this step, deeming it implausible; but we have shown otherwise,’ says Milstein. Moreover, the team has provided evidence showing that the bond between the two oxygen atoms is generated within a single molecule – not between oxygen atoms residing on separate molecules, as commonly believed – and it comes from a single metal center.

Discovery of an efficient artificial catalyst for the sunlight-driven splitting of water into oxygen and hydrogen is a major goal of renewable clean energy research. So far, Milstein’s team has demonstrated a mechanism for the formation of hydrogen and oxygen from water, without the need for sacrificial chemical agents, through individual steps, using light. For their next study, they plan to combine these stages to create an efficient catalytic system, bringing those in the field of alternative energy an important step closer to realizing this goal.

Participating in the research were former postdoctoral student Stephan Kohl, Ph.D. student Leonid Schwartsburd and technician Yehoshoa Ben-David all of the Organic Chemistry Department, together with staff scientists Lev Weiner, Leonid Konstantinovski, Linda Shimon and Mark Iron of the Chemical Research Support Department.

Prof. David Milstein’s research is supported by the Mary and Tom Beck-Canadian Center for Alternative Energy Research; and the Helen and Martin Kimmel Center for Molecular Design. Prof. Milstein is the incumbent of the Israel Matz Professorial Chair of Organic Chemistry.

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Journal reference:

1. Stephan W. Kohl, Lev Weiner, Leonid Schwartsburd, Leonid Konstantinovski, Linda J. W. Shimon, Yehoshoa Ben-David, Mark A. Iron, and David Milstein. Consecutive Thermal H₂ and Light-Induced O₂ Evolution from Water Promoted by a Metal Complex. Science, 2009; 324 (5923): 74 DOI: 10.1126/science.1168600

Radio frequency identification (RFID) devices have widely been used for tracking for years; recently, scientists from U.S. Department of Energy's (DOE) Argonne National Laboratory have developed a unique tracking technology that also monitors the environmental and physical conditions of containers of nuclear materials in storage and transportation.

"RFID technology is ideally suited for management of nuclear materials during both storage and transportation," said Dr. Yung Liu, Argonne senior nuclear engineer and RFID project manager. "Key information about the nuclear materials is acquired in real-time," he explained.

Data on the status and history of each individual container are available with a click of the mouse and can be used to augment and modernize DOE's existing management systems for nuclear materials.

"The Argonne system can simultaneously monitor thousands of drums 24 hours a day, seven days a week. Any abnormal situation, such a loss of seal, a sudden shock, a rise in temperature or humidity, can trigger an alarm for immediate action," Liu explained.

The monitoring of tens of thousands of radioactive and fissile material packages has been a challenge for DOE to ensure accountability, safety, security and worker and public health.

"The RFID system that Dr. Liu and his group developed with collaborators will help DOE overcome this challenge," said Dr. James Shuler, Manager of DOE Packaging Certification Program, Office of Environmental Management.

The system is comprised of active transponders, or tags with long-life batteries (>10 years), on each package, readers that collect information from the tags, control computer, and application software. The information is constantly updated and communicated via a secured network, thus decreasing the need for manned surveillance. Explained Liu, "information can be retrieved promptly by local and authorized off-site users via a secured network for action."

This RFID technology also has applications outside the nuclear field and may be used for other hazardous materials or any valued material, according to Liu.

"This new Argonne RFID technology, expected to be patented, has applications in many industries and as the technology is further developed, its usefulness is bound to grow," Liu said.

Funding for this project was made by the U.S. Department of Energy, Office of Environmental Management. The Office of Environmental Management (EM) is responsible for the risk reduction and safe cleanup of the environmental legacy of the Nation's nuclear weapons program and government-sponsored nuclear energy research and is one of the largest, most diverse, and technically complex environmental programs in the world.

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Researchers have developed a critical part of a hydrogen storage system for cars that makes it possible to fill up a vehicle's fuel tank within five minutes with enough hydrogen to drive 300 miles.

The system uses a fine powder called metal hydride to absorb hydrogen gas. The researchers have created the system's heat exchanger, which circulates coolant through tubes and uses fins to remove heat generated as the hydrogen is absorbed by the powder.

The heat exchanger is critical because the system stops absorbing hydrogen effectively if it overheats, said Issam Mudawar, a professor of mechanical engineering who is leading the research.

"The hydride produces an enormous amount of heat," Mudawar said. "It would take a minimum of 40 minutes to fill the tank without cooling, and that would be entirely impractical."

Researchers envision a system that would enable motorists to fill their car with hydrogen within a few minutes. The hydrogen would then be used to power a fuel cell to generate electricity to drive an electric motor.

The research, funded by General Motors Corp. and directed by GM researchers Darsh Kumar, Michael Herrmann and Abbas Nazri, is based at the Hydrogen Systems Laboratory at Purdue's Maurice J. Zucrow Laboratories. In February, the team applied for three provisional patents related to this technology.

"The idea is to have a system that fills the tank and at the same time uses accessory connectors that supply coolant to extract the heat," said Mudawar, who is working with mechanical engineering graduate student Milan Visaria and Timothée Pourpoint, a research assistant professor of aeronautics and astronautics and manager of the Hydrogen Systems Laboratory. "This presented an engineering challenge because we had to figure out how to fill the fuel vessel with hydrogen quickly while also removing the heat efficiently. The problem is, nobody had ever designed this type of heat exchanger before. It's a whole new animal that we designed from scratch."

The metal hydride is contained in compartments inside the storage "pressure vessel." Hydrogen gas is pumped into the vessel at high pressure and absorbed by the powder.

"This process is reversible, meaning the hydrogen gas may be released from the metal hydride by decreasing the pressure in the storage vessel," Mudawar said. "The heat exchanger is fitted inside the hydrogen storage pressure vessel. Due to space constraints, it is essential that the heat exchanger occupy the least volume to maximize room for hydrogen storage."

Conventional automotive coolant flows through a U-shaped tube traversing the length of the pressure vessel and heat exchanger. The heat exchanger, which is made mostly of aluminum, contains a network of thin fins that provide an efficient cooling path between the metal hydride and the coolant.

"This milestone paves the way for practical on-board hydrogen storage systems that can be charged multiple times in much the same way a gasoline tank is charged today," said Kumar, a researcher at GM's Chemical & Environmental Sciences Laboratory and the GM R&D Center in Warren, Mich. "As newer and better metal hydrides are developed by research teams worldwide, the heat exchanger design will provide a ready solution for the automobile industry."

The researchers have developed the system over the past two years. Because metal hydride reacts readily with both air and moisture, the system must be assembled in an airtight chamber, Pourpoint said.

Research activities at the hydrogen laboratory involve faculty members from the schools of aeronautics and astronautics, mechanical engineering, and electrical and computer engineering.

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For the first time, MIT researchers have shown they can genetically engineer viruses to build both the positively and negatively charged ends of a lithium-ion battery.

The new virus-produced batteries have the same energy capacity and power performance as state-of-the-art rechargeable batteries being considered to power plug-in hybrid cars, and they could also be used to power a range of personal electronic devices, said Angela Belcher, the MIT materials scientist who led the research team.

The new batteries, described in the April 2 online edition of Science, could be manufactured with a cheap and environmentally benign process: The synthesis takes place at and below room temperature and requires no harmful organic solvents, and the materials that go into the battery are non-toxic.

In a traditional lithium-ion battery, lithium ions flow between a negatively charged anode, usually graphite, and the positively charged cathode, usually cobalt oxide or lithium iron phosphate. Three years ago, an MIT team led by Belcher reported that it had engineered viruses that could build an anode by coating themselves with cobalt oxide and gold and self-assembling to form a nanowire.

In the latest work, the team focused on building a highly powerful cathode to pair up with the anode, said Belcher, the Germeshausen Professor of Materials Science and Engineering and Biological Engineering. Cathodes are more difficult to build than anodes because they must be highly conducting to be a fast electrode, however, most candidate materials for cathodes are highly insulating (non-conductive).

To achieve that, the researchers, including MIT Professor Gerbrand Ceder of materials science and Associate Professor Michael Strano of chemical engineering, genetically engineered viruses that first coat themselves with iron phosphate, then grab hold of carbon nanotubes to create a network of highly conductive material.

Because the viruses recognize and bind specifically to certain materials (carbon nanotubes in this case), each iron phosphate nanowire can be electrically "wired" to conducting carbon nanotube networks. Electrons can travel along the carbon nanotube networks, percolating throughout the electrodes to the iron phosphate and transferring energy in a very short time.

The viruses are a common bacteriophage, which infect bacteria but are harmless to humans.

The team found that incorporating carbon nanotubes increases the cathode's conductivity without adding too much weight to the battery. In lab tests, batteries with the new cathode material could be charged and discharged at least 100 times without losing any capacitance. That is fewer charge cycles than currently available lithium-ion batteries, but "we expect them to be able to go much longer," Belcher said.

The prototype is packaged as a typical coin cell battery, but the technology allows for the assembly of very lightweight, flexible and conformable batteries that can take the shape of their container.

Last week, MIT President Susan Hockfield took the prototype battery to a press briefing at the White House where she and U.S. President Barack Obama spoke about the need for federal funding to advance new clean-energy technologies.

Now that the researchers have demonstrated they can wire virus batteries at the nanoscale, they intend to pursue even better batteries using materials with higher voltage and capacitance, such as manganese phosphate and nickel phosphate, said Belcher. Once that next generation is ready, the technology could go into commercial production, she said.

Lead authors of the Science paper are Yun Jung Lee and Hyunjung Yi, graduate students in materials science and engineering. Other authors are Woo-Jae Kim, postdoctoral fellow in chemical engineering; Kisuk Kang, recent MIT PhD recipient in materials science and engineering; and Dong Soo Yun, research engineer in materials science and engineering.

The research was funded by the Army Research Office Institute of the Institute of Collaborative Technologies, and the National Science Foundation through the Materials Research Science and Engineering Centers program.

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Journal reference:

1. Yun Jung Lee, Hyunjung Yi, Woo-Jae Kim, Kisuk Kang, Dong Soo Yun, Michael S. Strano, Gerbrand Ceder, and Angela M. Belcher. Fabricating Genetically Engineered High-Power Lithium Ion Batteries Using Multiple Virus Genes. Science, 2009; DOI: 10.1126/science.1171541

Concerns that terrorists could produce a new and particularly dangerous form of the explosive responsible for airport security screening of passengers' shoes and restrictions on liquids in carryon baggage are unfounded, scientists reported March 24.

Speaking at the 237th National Meeting of the American Chemical Society in Salt Lake City, Utah, Gerard Harbison, Ph.D., and colleagues described using computer simulations to analyze a variety of potential peroxide-based explosives in the same chemical class as triacetone triperoxide (TATP). That powerful, easy-to-make explosive was used by the "shoe bomber," Richard Reid, in his failed attempt to blow up a transatlantic airline flight in 2001. TATP has also been used by suicide bombers in the Palestinian Intifada.

Harbison's team became intrigued by "Internet lore," reports circulating on the Web claiming creation of another explosive — tetracetone tetraperoxide (TeATeP) — which is reputedly a more lethal relative to TATP. Initially working on detection methods of peroxide explosives for the Defense Advanced Research Projects Agency, the group instead began to investigate the structure of TeATeP to evaluate likelihood of its use as a terrorist's weapon.

"Our analysis indicates that potentially new and destructive terrorist materials, which would tax our detection capabilities, may be too unstable for a practical synthesis," said Harbison, a chemist at the University of Nebraska-Lincoln. "We consider it unlikely that any of the previous syntheses were actually successful, and the Internet myths about TeATeP are nothing more than that. So the good news is basically this is something we don't have to worry about."

The group investigated 20 molecular structures of various acetone peroxide compounds and found that all substances larger than TATP are likely too sensitive to be used as weapons. "The energies we're seeing in the analysis are extreme enough," Harbison said, adding that a review of previous TeATeP synthesis reports raised many questions. "If you look at the actual literature on people who claim to have made TeATeP, it's very ambiguous. We think probably what happened when people thought they were making TeATeP was that they were actually making TATP."

This synthesis error is common and often fatal, Harbison said. When trying to make TATP, a less stable relative, diacetone diperoxide, often is created. "The nice thing about doing this on the computer is first it's safe, and our results are so close to what's been experimentally measured that we have a great deal of confidence with what we're doing," Harbison said. "We're really at the stage where we can evaluate threats — potential molecules that might be dangerous — and we can really make some sort of judgment about whether those molecules are going to present a hazard in the future. We can test things with computers at a level of reliability that's comparable to personally doing the synthesis and evaluating material yourself."

There's a lot of research that deals with known threats, Harbison said. But his groups' research focuses on the idea that emerging threats will always exist. "Presumably you'd like to anticipate the threats before they come along. We're now pushing it a little further and discussing potential threats.

"Using computational chemistry, we can narrow down the domain of potential hazards, things that aren't going to be on the horizon. I think we now know so much more about not just what works for improvised-explosive-device detection but also what doesn't work, and we don't have to try it out (experimentally). We did five years ago."

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President Barack Obama has made his intention of eliminating all nuclear weapons a tenet of his administration's foreign policy. Professor Sidney Drell, a US theoretical physicist and arms-control expert, explains in February's Physics World what Obama needs to do to make that honourable intention a reality.

Professor Drell, a professor emeritus at the SLAC National Accelerator Center, a senior fellow at Stanford University's Hoover Institution and an adviser on technical national security and arms-control for the US Government, has recently co-authored a report called Nuclear Weapons in 21st Century US National Security, in collaboration with the American Association for the Advancement of Science, the American Physical Society and the Center for Strategic and International Studies.

In his article for Physics World, he explains how and why there is need now, more than ever, to introduce globally ratified systems to control the spread of nuclear arms.

Professor Drell explains: "The world is teetering on the edge of a new and more perilous nuclear era, facing a growing danger that nuclear weapons – the most devastating instrument of annihilation ever invented – may fall into the hands of 'rogue states' or terrorist organizations that do not shrink from mass murder on an unprecedented scale.

His article makes two recommendations to Obama and his team. The first is to 'revisit Reykjavik' – Reykjavik hosted a summit in 1986 where former US President Ronald Reagan and then Soviet premier Mikhail Gorbachev agreed to begin reducing the size of their respected countries' nuclear arsenals. As the US and Russia still possess more than 90 per cent of the world's nuclear warheads, it is imperative that they take the lead, Drell says.

Drell's second recommendation is that the new Obama administration should adopt a process for bringing the Comprehensive Test Ban Treaty (CTBT) into effect. "The new administration should initiate a timely bipartisan, congressional review of the value of the CTBT for US security," he says.

Drell concludes: "With these two steps outlined above, President Obama has a historic opportunity to start down a practical path towards achieving his stated goal of 'eliminating all nuclear weapons.'"

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Does a twin Earth exist somewhere in our galaxy? Astronomers are getting closer and closer to finding an Earth-sized planet in an Earth-like orbit. NASA's Kepler spacecraft just launched to find such worlds. Once the search succeeds, the next questions driving research will be: Is that planet habitable? Does it have an Earth-like atmosphere? Answering those questions will not be easy.

Due to its large mirror and location in outer space, the James Webb Space Telescope (scheduled for launch in 2013) will offer astronomers the first real possibility of finding those answers. In a new study, Lisa Kaltenegger (Harvard-Smithsonian Center for Astrophysics) and Wesley Traub (Jet Propulsion Laboratory) examined the ability of JWST to characterize the atmospheres of hypothetical Earth-like planets during a transit, when part of the light of the star gets filtered through the planet's atmosphere. They found that JWST would be able to detect certain gases called biomarkers, such as ozone and methane, only for the closest Earth-size worlds.

"We'll have to be really lucky to decipher an Earth-like planet's atmosphere during a transit event so that we can tell it is Earth-like," said Kaltenegger. "We will need to add up many transits to do so - hundreds of them, even for stars as close as 20 light-years away."

"Even though it's hard, it will be an incredibly exciting endeavor to characterize a distant planet's atmosphere," she added.

In a transit event, a distant, extrasolar planet crosses in front of its star as seen from Earth. As the planet transits, gases in its atmosphere absorb a tiny fraction of the star's light, leaving fingerprints specific to each gas. By splitting the star's light into a rainbow of colors or spectrum, astronomers can look for those fingerprints. Kaltenegger and Traub studied whether those fingerprints would be detectable by JWST.

Their study has been accepted for publication in The Astrophysical Journal.

The transit technique is very challenging. If Earth were the size of a basketball, the atmosphere would be as thin as a sheet of paper, so the resulting signal is incredibly tiny. Moreover, this method only works when the planet is in front of its star, and each transit lasts for a few hours at most.

Kaltenegger and Traub first considered an Earth-like world orbiting a Sun-like star. To get a detectable signal from a single transit, the star and planet would have to be extremely close to Earth. The only Sun-like star close enough is Alpha Centauri A. No such world has been found yet, but technology is only now becoming capable of detecting Earth-sized worlds.

The study also considered planets orbiting red dwarf stars. Such stars, called type M, are the most abundant in the Milky Way - far more common than yellow, type G stars like the Sun. They are also cooler and dimmer than the Sun, as well as smaller, which makes finding an Earth-like planet transiting an M star easier.

An Earth-like world would have to orbit close to a red dwarf to be warm enough for liquid water. As a result, the planet would orbit more quickly and each transit would last a couple of hours to mere minutes. But it would undergo more transits in a given amount of time. Astronomers could improve their chances of detecting the atmosphere by adding the signal from several transits, making red dwarf stars appealing targets because of their more frequent transits.

An Earth-like world orbiting a star like the Sun would undergo a 10-hour transit once every year. Accumulating 100 hours of transit observations would take 10 years. In contrast, an Earth orbiting a mid-sized red dwarf star would undergo a one-hour transit once every 10 days. Accumulating 100 hours of transit observations would take less than three years.

"Nearby red dwarf stars offer the best possibility of detecting biomarkers in a transiting Earth's atmosphere," said Kaltenegger.

"Ultimately, direct imaging - studying photons of light from the planet itself - may prove a more powerful method of characterizing the atmosphere of Earth-like worlds than the transit technique," said Traub.

Both NASA's Spitzer and Hubble Space Telescopes have studied the atmospheric compositions of extremely hot, gas-giant extrasolar planets. The characterization of a "pale blue dot" is the next step from there, whether by adding up hundreds of transits of one planet or by blocking out the starlight and analyzing the planet's light directly.

In a best-case scenario, Alpha Centauri A may turn out to have a transiting Earth-like planet that no one has spotted yet. Then, astronomers would need only a handful of transits to decipher that planet's atmosphere and possibly confirm the existence of the first twin Earth.

This research was partially funded by NASA.

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Journal reference:

1. L. Kaltenegger, W.A. Traub. Transits of Earth-Like Planets. The Astrophysical Journal, 2009; (in press) [link]

A researcher has developed probes that can help pinpoint the location of tumors and might one day be able to directly attack cancer cells.

Joseph Irudayaraj, a Purdue University associate professor of agricultural and biological engineering, developed the nanoscale, multifunctional probes, which have antibodies on board, to search out and attach to cancer cells.

A paper detailing the technology was released last week in the online version of Angewandte Chemie, an international chemistry journal.

"If we have a tumor, these probes should have the ability to latch on to it," Irudayaraj said. "The probe could carry drugs to target, treat as well as reveal cancer cells."

Scientists have developed probes that use gold nanorods or magnetic particles, but Irudayaraj's nanoprobes use both, making them easier to track with different imaging devices as they move toward cancer cells.

The magnetic particles can be traced through the use of an MRI machine, while the gold nanorods are luminescent and can be traced through microscopy, a more sensitive and precise process. Irudayaraj said an MRI is less precise than optical luminescence in tracking the probes, but has the advantage of being able to track them deeper in tissue, expanding the probes' possible applications.

The probes, which are about 1,000 times smaller than the diameter of a human hair, contain the antibody Herceptin, used in treatment of metastatic breast cancer. The probes would be injected into the body through a saline buffering fluid, and the Herceptin would find and attach to protein markers on the surface of cancer cells.

"When the cancer cell expresses a protein marker that is complementary to Herceptin, then it binds to that marker," Irudayaraj said. "We are advancing the technology to add other drugs that can be delivered by the probes."

Irudayaraj said better tracking of the nanoprobes could allow doctors to pinpoint the location of known tumors and better treat the cancer.

The novel probes were tested in cultured cancer cells. Irudayaraj said the next step would be to run a series of tests in mice models to determine the dose and stability of the probes.

The research was funded through a National Institute of Health grant, as well as by the Purdue Research Foundation. Irudayaraj is head of a biological engineering team that includes postdoctoral researcher Chungang Wang and graduate student Jiji Chen.

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MIT engineers have created a kind of beltway that allows for the rapid transit of electrical energy through a well-known battery material, an advance that could usher in smaller, lighter batteries — for cell phones and other devices — that could recharge in seconds rather than hours.

The work could also allow for the quick recharging of batteries in electric cars, although that particular application would be limited by the amount of power available to a homeowner through the electric grid.

The work, led by Gerbrand Ceder, the Richard P. Simmons Professor of Materials Science and Engineering, is reported in the March 12 issue of Nature. Because the material involved is not new — the researchers have simply changed the way they make it — Ceder believes the work could make it into the marketplace within two to three years.

State-of-the-art lithium rechargeable batteries have very high energy densities — they are good at storing large amounts of charge. The tradeoff is that they have relatively slow power rates — they are sluggish at gaining and discharging that energy. Consider current batteries for electric cars. "They have a lot of energy, so you can drive at 55 mph for a long time, but the power is low. You can't accelerate quickly," Ceder said.

Why the slow power rates? Traditionally, scientists have thought that the lithium ions responsible, along with electrons, for carrying charge across the battery simply move too slowly through the material.

About five years ago, however, Ceder and colleagues made a surprising discovery. Computer calculations of a well-known battery material, lithium iron phosphate, predicted that the material's lithium ions should actually be moving extremely quickly.

"If transport of the lithium ions was so fast, something else had to be the problem," Ceder said.

Further calculations showed that lithium ions can indeed move very quickly into the material but only through tunnels accessed from the surface. If a lithium ion at the surface is directly in front of a tunnel entrance, there's no problem: it proceeds efficiently into the tunnel. But if the ion isn't directly in front, it is prevented from reaching the tunnel entrance because it cannot move to access that entrance.

Ceder and Byoungwoo Kang, a graduate student in materials science and engineering, devised a way around the problem by creating a new surface structure that does allow the lithium ions to move quickly around the outside of the material, much like a beltway around a city. When an ion traveling along this beltway reaches a tunnel, it is instantly diverted into it. Kang is a coauthor of the Nature paper.

Using their new processing technique, the two went on to make a small battery that could be fully charged or discharged in 10 to 20 seconds (it takes six minutes to fully charge or discharge a cell made from the unprocessed material).

Ceder notes that further tests showed that unlike other battery materials, the new material does not degrade as much when repeatedly charged and recharged. This could lead to smaller, lighter batteries, because less material is needed for the same result.

"The ability to charge and discharge batteries in a matter of seconds rather than hours may open up new technological applications and induce lifestyle changes," Ceder and Kang conclude in their Nature paper.

This work was supported by the National Science Foundation through the Materials Research Science and Engineering Centers program and the Batteries for Advanced Transportation Program of the U.S. Department of Energy. It has been licensed by two companies.

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Journal reference:

1. Byoungwoo Kang & Gerbrand Ceder. Battery materials for ultrafast charging and discharging. Nature, 2009; 458 (7235): 190 DOI: 10.1038/nature07853

Car doors are usually assembled from several sections of sheet metal which are welded together by laser. The laser beam moves over the slightly overlapping sheets and melts them in a spot measuring several tenths of a millimeter, producing a so called full penetration hole that closes again when the laser beam moves on.

It is most important for the laser output power to be set correctly – if it is too low the strength of the welding connection is reduced because it does not extend over the full cross section of the metal sheets, if it is too high the laser cuts right through them.

Until now welders have gauged the right laser output by trial and error and then kept it constant. A complicating factor exists, however, in that the protective glass gets dirty after a while and lets less laser light through onto the metal. If this happens earlier than usual, hours can pass before it is noticed and the metal sheets may not be properly welded. Today, welding processes are only monitored without adjustment of the laser power because the achievalble frame rate of about thousand evaluated images per second is not sufficient. For a closed loop control, frame rates of more than 10 kilohertz – equivalent to 10,000 images per second – are needed for a robust surveillance of the rapidly moving full penetration hole.

Researchers at the Fraunhofer Institute for Physical Measurement Techniques IPM in Freiburg have now developed a control system for laser welding processes which adapts the output to the given situation.

"Our system analyzes 14,000 images per second and uses the acquired data to adjust the laser output," explains IPM project manager Andreas Blug.

So how does the system manage to analyze the images more than ten times faster than conventional software? "We use special cameras in which a tiny processor is integrated in each pixel. All these processors – 25,000 in total – work simultaneously. In conventional image processing systems the data are handled consecutively by just a small number of computer processors," says Blug.

The new systems are referred to as "Cellular Neural Networks" (CNN). Just a few microseconds after the image is taken the camera delivers an analyzed picture of the contours of the full penetration hole. For small holes the system increases the output, for large ones it reduces it. "In developing this adjustment system we have achieved the first industrial application of CNN technology," says Blug. A prototype already exists, and the researchers now intend to test the system in production.

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Scientists in Washington state are reporting the surprise discovery of the oldest known sample of reactor-produced bomb-grade plutonium, a historic relic from the infancy of America's nuclear weapons program. Their research also represents the first demonstration of how radioactive sodium can be used as a tool in nuclear forensics.

In the new study, Jon Schwantes and colleagues note increased concern about the possibility of terrorists smuggling radioactive materials to make illegal nuclear weapons. As a result, scientists are stepping up efforts to identify and track the source of these radioactive materials using the advanced tools and techniques of a new field called "nuclear archaeology."

The scientists describe efforts to determine the origin of an unknown sample of plutonium (Pu) found in 2004 in a bottle at a waste burial trench at the Hanford nuclear site in Washington. Hanford is the earliest location for U.S. plutonium production for nuclear weapons and now the focus of a massive environmental cleanup effort due to high levels of radioactive waste that remain at the site.

Using multiple pairs of "parent" Pu and "daughter" uranium (U) isotopes, the researchers were able to correct for chemical fractionation that occurred as a result of repackaging in 2004 and determine the age of the sample. Using this technique, they estimated that the Pu in the sample had been separated from U and fission products in 1944, making it the oldest known sample of bomb-grade plutonium produced in a reactor. The only older known samples of Pu-239 were produced by the late Glenn Seaborg and his associates in the beginning of the 1940's when the existence of the element was first confirmed and characterized.

The study identified the Clinton reactor in Oak Ridge, Tenn., as reactor of origin for this material, by comparing reactor burnup modeling results with measurements of minor Pu isotopes. These results were also supported by a series of historical documents tracking the material's movement from Oak Ridge and the processing at Hanford. "Aside from the historical significance of this find, this work provides the public a rare glimpse at a real-world example of the science behind and power of modern-day nuclear forensics," the scientists note.

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Journal reference:

1. Schwantes et al. Nuclear Archeology in a Bottle: Evidence of Pre-Trinity U.S. Weapons Activities from a Waste Burial Site. Analytical Chemistry, 2009; 81 (4): 1297 DOI: 10.1021/ac802286a

As electronic circuits shrink from finely etched lines in silicon wafers to nearly elusive proportions, researchers at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab) and Columbia University are studying how electrons flow through a molecular junction-a nanometer scale circuit element that contacts gold atoms with a single molecule.

Their findings reveal the electrical resistance through this junction can be turned ‘on’ and ‘off’ simply by pushing and pulling the junction-a feature that could be used as a switch in nanoscale electronic devices.

“To design circuit elements at the molecular scale, we need to understand how the intrinsic properties of a molecule or junction are actually connected to its measured resistance,” said Jeff Neaton, Facility Director of the Theory of Nanostructured Materials Facility in the Molecular Foundry, a U.S. Department of Energy User Facility located at Berkeley Lab that provides support to nanoscience researchers around the world. “Knowing where each and every atom is in a single-molecule junction is simply beyond what’s possible with experiments at this stage. For these sub-nanometer scale junctions-just a handful of atoms-theory can be valuable in helping interpret and understand resistance measurements.”

In traditional electronic devices, charge-carrying electrons diffuse through circuits in a well-understood fashion, gaining or losing energy through transactions with impurities or other particles they encounter. Electrons at the nanoscale, however, can travel by a mechanism called quantum tunneling in which, due to the small length scales involved, it becomes possible for a particle to disappear through an energy barrier and suddenly appear on the other side, without expending energy.

Tracking such ‘tunneling’ of electrons through individual molecules in nanoscale devices has proven difficult. “For more than a decade, researchers have been ‘wiring up’ individual molecules and measuring their electrical conductance,” said Neaton. “Forming reliable contacts between nanostructures and ‘alligator clip’ electrical leads is extremely challenging. This made experiments difficult to interpret, and as a result, reported conductance values-in experiment and theory-often varied by an order of magnitude or more. The time was ripe for a quantitative comparison between theory and an experiment with well-defined contacts.”

Through the Molecular Foundry user program, Su Ying Quek, a postdoctoral researcher, worked with Neaton and Latha Venkataraman, an experimental researcher at Columbia University, using a scanning tunneling microscope (STM), which probes changes in current across a material’s surface with a conductive gold tip. Previous work had shown a gold STM tip could be repeatedly be plunged into a gold surface containing a solution of molecules and retracted, until the contact area between the tip and gold surface reduces to a single strand, like a necklace.

When this strand finally breaks, nearby molecules can hop into the gap between strands and contact the gold electrodes, resulting in a sudden change in conductance. Using this technique, Venkataraman and colleagues, including Mark Hybertsen at Brookhaven National Lab, had recently discovered that the conductance of molecules containing amines (a group of molecules related to ammonia) in contact with gold electrodes could be reliably measured.

“We now had a reproducible and consistent data set to benchmark our theory,” said Quek. “Comparing with this data set, we discovered important electron correlation effects previously missing. When we added these, we found-for the first time-quantitative agreement with experimental results.”

Using their new theoretical approach, Quek and Neaton, together with Hybertsen and collaborators Steven G. Louie of University of California Berkeley and Hyoung Joon Choi of Yonsei University in Korea, began to study the conductance of a junction between gold electrodes and bipyridine-a benzene-like ring molecule containing nitrogen. The experimental data showed two stable conductance states, unlike anything seen previously. Working closely with Venkataraman and collaborators, Quek hypothesized the peaks corresponded to two states with different structures within the junction. During the next year, Quek and Neaton meticulously constructed a theory that could describe the conductance of junctions arranged vertically between two gold molecules and sandwiched at angles.

The story that emerged was surprisingly detailed: if bipyridine bonded at an angle, more current could flow compared with when the bipyridine bonded vertically. This suggests the conductance of bipyridine was linked to the molecule’s orientation in the junction, explained Quek. In the STM experiment, as you pull, just after the final strand of gold atoms breaks and snaps back, the vertical gap is not big enough for bipyridine, so it bonds at an angle. As the gap increases, the molecule jumps to a vertical configuration, causing the conductance to plummet abruptly. Eventually, the molecule straightens even more, and the contact breaks. “Once we determined this, we wondered, ‘could you reverse this behavior?’” said Quek.

Teaming with Venkataraman and collaborators, Quek and Neaton demonstrated why pushing the junction to an angle and pulling it straight could repeatedly alter the conductance, creating a mechanical switch with well defined ‘on’ and ‘off’ states. “One of the fascinating things about this experiment is the degree to which it is possible to control the ‘alligator clips’,” said Neaton. “For this particular molecule, bipyridine, experiments can reproducibly and reliably alter these atomic-scale features back and forth to switch the conductance of the junction.”

Quek and Neaton hope to refine and apply their theoretical framework to more complex molecular junctions for study of systems promising for solar energy conversion, such as organic photovoltaics.

“Understanding how electrons move through single-molecule junctions is the first step,” said Neaton. “Organic-inorganic interfaces are everywhere in nanoscience, and developing a better picture of charge transport in hybrid materials systems will certainly lead to the discovery of new and improved electronic devices.”

Portions of this work were supported by the U.S. Department of Energy (DOE) Office of Science, through its Office of Basic Energy Sciences, and by the National Science Foundation through its Nanoscale Science and Engineering Initiative.

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Journal reference:

1. Quek et al. Mechanically controlled binary conductance switching of a single-molecule junction. Nature Nanotechnology, 2009; DOI: 10.1038/nnano.2009.10

Scientists have found that graphite behaves like a semiconductor in ultrafast time scales. The results are of fundamental importance for future electronic devices based on carbon, in which high electrical fields or frequencies are processed.

Nanomaterials like carbon possess unique properties, which have led to first applications in novel electronic devices and sensors. These materials are based on ordered, atomically thin layers of carbon atoms, for example in the form of a single layer as so-called “graphene”, or rolled-up in carbon nanotubes. The electronic properties of such structures are closely related to those of graphite, which consists of a stack of graphene sheets.

Despite intensive research in the past, the fundamental behavior of electrons in this material are not fully understood and still controversially debated.

Markus Breusing, Claus Ropers und Thomas Elsaesser, three scientists from the Max-Born-Institute in Berlin, have now investigated the behavior of electrons in thin graphite films in real time.

As they now report in Physical Review Letters,* they recorded the dynamics of electrons with an unprecedented temporal resolution of only 10 femtoseconds (one femtosecond is a millionth of a billionth of a second). Electrons were excited to high energy states with ultrashort laser pulses, and their return to equilibrium was observed. The individual steps of this process are temporally resolved, and the momentary distribution of electrons in the material is identified. Within 30 femtoseconds, electrons form a hot gas with temperatures of 2500 °C, which cools down to about 200 °C in only 500 femtoseconds. The energy dissipated in this process is transferred to the crystal lattice. After this process, the electrons slowly return to their initial states.

For the first time, the study shows conclusively that, on ultrashort time scales, graphite behaves like a semiconductor, such as silicon or gallium arsenide, and not like a metal.

The observed dynamics have significant consequences for electrical transport, such as currents flowing through the material at high frequencies. The results are of fundamental importance for future electronic devices based on carbon, in which high electrical fields or frequencies are processed.

*Volume 102, Issue 08, 086809/1-4, 2009

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Microscopic particles of carbon known as buckyballs may be able to keep the nation's water pipes clear in the same way clot-busting drugs prevent arteries from clogging up.

Engineers at Duke University have found that buckyballs hinder the ability of bacteria and other microorganisms to accumulate on the membranes used to filter water in treatment plants. This attribute leads the researchers to believe that coating pipes and membranes with these nanoparticles may prove to be an effective strategy for addressing one of the major problems and costs of treating water.

"Just as plaque can build up inside arteries and reduce the flow of blood, bacteria and other microorganisms can over time attach and accumulate on water treatment membranes and along water pipes," said So-Ryong Chae, post-doctoral fellow in Duke's environmental and civil engineering department. The results of his experiments were published March 5, 2009 in the Journal of Membrane Sciences.

"As the bacteria build up on these surfaces, they attract other organic matter, creating a biofilm that slowly builds up over time," Chae continued, "The results of our experiments in the laboratory indicate that buckyballs may be able to prevent this clogging, known as biofouling. The only other options to address biofouling are digging up the pipes and replacing the membranes, which can be expensive and inconvenient."

A buckyball, or C60, is one shape within the family of tiny carbon shapes known as fullerenes. They are named after Richard Buckminster Fuller, the inventor of the geodesic dome, since their shape resembles his famous structure.

"Biofouling is viewed as one of the biggest costs associated with membrane-based water treatment systems," said Claudia Gunsch, assistant professor of civil engineering at Duke's Pratt School of Engineering and senior member of the research team. "These membranes have very small pores, so they can get stopped up quickly. If we could increase the time between membrane replacements by 50 percent, for example, that would be a huge cost savings."

According to Chae, the addition of buckyballs to treatment membranes had a two-fold effect. First, treated membranes showed less bacterial attachment than non-treated membranes. After three days, the membranes treated with buckyballs had on average 20 colony forming units, the method by which bacterial colonies are counted.

"In contrast, the number of bacterial colonies on the untreated membrane was too numerous to count," Chae said.

Chae also found that the presence of the buckyballs inhibited respiration, or the ability of the bacteria to use oxygen to fuel its activities.

"As the concentration of buckyballs increased, so did the inhibition of respiration," Chae said. "This respiratory inhibition and anti-attachment suggests that this nanoparticle may be useful as an anti-fouling agent to prevent the biofouling of membranes or other surfaces."

Gunsch said the mechanisms involved are not well-understood.

Both Gunsch and Chae believe that since buckyballs are one of the most widely used nanoparticles, additional research is needed to determine if they have any detrimental effects on the environment or to humans. This is one of many issues being studied at Duke's Center for Environmental Implications of Nanotechnology.

"We need to figure out how resistant these coatings will be to long-term use," Gunsch said. "If they can indeed prevent fouling, they will last longer. If they slough off over time, we need to know what the effects will be."

The current experiments in the laboratory were conducted with Escherichia coli K12, a strain of the bacteria that is widely used in laboratory experiments.

"We focused on a quite specific microorganism, so the next stage of our research will to see if these nanoparticles will have the same effects on bacteria commonly found in the environment or those in mixed microbial communities," Chae said. "We also plan to build a small-scale version of a treatment plant in the lab to conduct these tests."

The research was supported by the Office of Naval Research, National Science Foundation and the Korea Research Foundation. Other Duke members of the team were Shuyi Wang, Zachary Hendren and Mark R. Wiesner. Yoshimasa Watanabe, Hokkaido University, Japan, was also part of the team.

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Researchers at Uppsala University have managed for the first time to measure magnetic properties in new materials quantitatively with the help of electron microscopy – with unparalleled precision. The secret behind the breakthrough is a successful elaboration of electron microscope technology.

The findings, published in the scientific journal Physical Review Letters, means that the energy loss entailed in all electromagnetic materials can ultimately be minimized.

Apace with the miniaturization of electronic components, new methods are needed to analyze the properties of materials down to the atomic level. In 2006 a scientific article showed that it is possible to use a transmission electron microscope to study the magnetic properties of a material, using a technique called “Electron Magnetic Circular Dichroism,” (EMCD). As different materials are combined, often in thin atomic monolayer films, exciting new magnetic properties are created.

This is an interesting research field that is used in hard drives, for example. Today scientists are primarily studying magnetic properties with the aid of an extremely expensive synchrotron light source, whereas EMCD affords a cheaper and considerably more detailed study of the magnetic properties of each layer down to one nanometer.

Until now it has only been shown that EMCD works qualitatively. The Uppsala University researchers have further elaborated the technology to enable it to measure the magnetic forces of the sample quantitatively as well.

“This means we can put a number on the magnetic strength of the sample, which is key to understanding how various materials interact,” says Klaus Leifer, professor of experimental physics at the Department of Engineering Sciences.

By combining practical experiments and theoretical calculations, the method of measuring the EMCD signal has now been optimized and the computer processing of the experimental data further developed. The article is the result of collaborative work involving researchers in materials theory (Professor Olle Eriksson), physical materials synthesis (Professor Björgvin Hjörvarsson), and experimental physics.

These findings are important for our ability to analyze the magnetic properties of a material using equipment that is standard in most electron microscopy laboratories today.

“The technology will also enhance our knowledge of the energy losses that occur in magnetic components in generators and transformers,” says Klaus Leifer.

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Journal reference:

1. Hans Lidbaum, Ján Rusz, Andreas Liebig, Björgvin Hjörvarsson, Peter M. Oppeneer, Ernesto Coronel, Olle Eriksson, and Klaus Leifer. Quantitative Magnetic Information from Reciprocal Space Maps in Transmission Electron Microscopy. Physical Review Letters, 2009; 102 (3): 037201 DOI: 10.1103/PhysRevLett.102.037201

Overcoming a critical conductivity challenge to clean energy technologies, Boston College researchers have developed a titanium nanostructure that provides an expanded surface area and demonstrates significantly greater efficiency in the transport of electrons.

The challenge has vexed researchers pursuing solar panels thick enough to absorb sunlight, yet thin enough to collect and transport electrons with minimal energy loss. Similarly, the relatively new science of water splitting requires capturing energy within semiconductor materials and then efficiently transporting charges ultimately used to generate hydrogen.

Boston College Asst. Prof of Chemistry Dunwei Wang and members of his lab found that incorporating two titanium-based semiconductors into a nano-scale structure improved the efficiency of power-collecting efforts by approximately 33 percent, the team reported in the online edition of the Journal of the American Chemical Society.

The team achieved a peak conversion efficiency of 16.7 percent under ultraviolet light, reported Wang and his co-authors, BC graduate students Yongjing Lin and Sa Zhou, post doctoral researcher Xiaohua Liu and undergraduate Stafford Sheehan. That compared to an efficiency of 12 percent from a structure composed only of titanium dioxide (TiO2).

Wang said the efficiency gains within the novel material can serve so-called water-splitting, where semiconductor catalysts have been shown to separate and store hydrogen and oxygen gases.

"The current challenge in splitting water involves how best to capture photons within the semiconductor material and then grab and transport them to produce hydrogen," Wang says. "For practical water splitting, you want to generate oxygen and hydrogen separately. For this, good electrical conductivity is of great importance because it allows you to collect electrons in the oxygen-generation region and transport them to the hydrogen-generation chamber for hydrogen production."

By using two crystalline semiconductors – materials critical to the processes of energy capture and transport – Wang says the researchers discovered a new and successful transfer mechanism in an engineered structure nearly invisible to the human eye.

Titanium dioxide has played a key role in early water-splitting research because of its prowess as a catalyst. However, its light absorption is confined to ultraviolet rays only and the material is also a relatively poor conductor.

Wang and his researchers started by growing a nanostructure made of titanium disilicide (TiSi2), a semiconductor capable of absorbing solar light and a material able to provide a sturdy structure with expanded surface area critical to absorbing photons. Still in need of its catalytic capabilities, titanium dioxide was used to coat the structure, Wang said.

The resulting net-like nanostructure effectively separated charges, collecting the electrons in the titanium disilicide core and transporting them away. The structure transferred positive charges to the titanium dioxide region of the material for chemical reactions. In water-splitting, these charges could potentially be used to generate hydrogen.

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Journal reference:

1. Lin et al. TiO2/TiSi2 Heterostructures for High-Efficiency Photoelectrochemical H2O Splitting. Journal of the American Chemical Society, 2009; 131 (8): 2772 DOI: 10.1021/ja808426h

Just as sonar sends out sound waves to explore the hidden depths of the ocean, electrons can be used by scanning tunnelling microscopes to investigate the well-hidden properties of the atomic lattice of metals.

As researchers from Göttingen, Halle and Jülich now report in the journal Science, they succeeded in making bulk Fermi surfaces visible in this manner. Fermi surfaces determine the most important properties of metals.

"Fermi surfaces give metals their personality, so to speak," explained Prof. Stefan Blügel, Director at the Jülich Institute of Solid State Research. Important properties, such as conductivity, heat capacity and magnetism, are determined by them. On the Fermi surfaces inside the atomic union, high-energy electrons are in motion. Depending on what form the surfaces have and what mobility is assigned to the electrons, they determine the physical properties of metals.

In their latest publication, the researchers report on how they used a scanning tunnelling microscope to direct electrons into a copper sample. As electrons spread out like waves, they pass through the metal and are scattered and reflected at obstacles in the bulk, such as single cobalt atoms. "The overlap between incoming and outgoing waves is so strong," said Dr. Samir Lounis from Forschungszentrum Jülich who turned the theoretical calculations into an experiment, "that they can be measured as spherical patterns on the surface using the scanning tunnelling microscope."

The somewhat deformed rings on the surface allow us to draw direct conclusions on the shape of the Fermi surfaces and the depth of the cobalt atoms, similar to how sonar recognises the ocean floor by means of reflected sound waves. "We hope that more sophisticated methods will make it possible to gain a detailed understanding of deep impurities and interfaces between atomic lattices," explained Lounis. For his simulations of the scanning tunnelling experiment, he used the supercomputer known as JUMP in the Jülich Supercomputing Centre.

In a related article in the "Perspectives" section of "Science", the innovative approach is praised. A scanning tunnelling microscope is primarily used to characterise the surface of a sample. Thanks to the theoretical work in Jülich, it can now be used to gain a direct insight into the bulk of solids and to understand interesting effects in the nanoworld.

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Journal reference:

1. Weismann et al. Seeing the Fermi Surface in Real Space by Nanoscale Electron Focusing. Science, 2009; 323 (5918): 1190 DOI: 10.1126/science.1168738

Small is promising when it comes to illuminating tiny tumors or precisely delivering drugs, but many worry about the safety of nano-scale materials. Now a team of scientists has created minuscule flakes of silicon that glow brightly, last long enough to slowly release cancer drugs, then break down into harmless by-products.

"It is the first luminescent nanoparticle that was purposely designed to minimize toxic side effects," said Michael Sailor, a chemistry professor at the University of California, San Diego who led the study.

Many nanoparticles tested in research labs are too poisonous for use in humans.

"This new design meets a growing need for non-toxic alternatives that have a chance to make it into the clinic to treat human patients," Sailor said.

The particles inherently glow, a useful property that is most commonly achieved by including toxic organic chemicals or tiny structures called quantum dots, which can leave potentially harmful heavy metals in their wake.

When the researchers tested their safer nanoparticles in mice, they saw tumors glow for several hours, then dim as the particles broke down. Levels dropped noticeably in a week and were undetectable after four weeks, they report in Nature Materials February 22.

This is the first sudy to image tumors and organs using biodegradable silicon nanoparticles in live animals, the authors say.

The particles begin as thin wafers made porous with an electrical current then smashed to bits with ultrasound. Additional treatment alters the physical structure of the flakes to make them glow red when illuminated with ultraviolet light.

Luminescent particles can reveal tumors too tiny to detect by other means or allow a surgeon to be sure all of a cancerous growth has been removed.

These nanoparticles could also help deliver drugs safely, the researchers report. The cancer drug doxorubicin will stick to the pores and slowly escape as the silicon dissolves.

"The goal is to use the nanoparticles to chaperone the drug directly to the tumor, to release it into the tumor rather than other parts of the body," Sailor said.

Targeted delivery would allow doctors to use smaller doses of the drug. At doses high enough to be effective, when delivered to the whole body, doxorubicin often has toxic side effects.

At about 100 nanometers, these particles are bigger than many designed to deliver drugs, which can be just a few nanometers across – a thousand times smaller than the diameter of a human hair.

Their larger size contributes to both their effectiveness and their safety. Large particles can hold more of a drug. Yet they self-destruct, and the remnants can be filtered away by the kidneys.

Close examination of vulnerable organs like liver, spleen and kidney, which help to remove toxins, revealed no lasting changes in mice treated with the new nanoparticles.

Graduate students Ji-Ho Park and Luo Gu in Sailor's lab; Sangeeta Bhatia, bioengineering professor at the Massachusetts Institute of Technology and graduate student Geoffrey von Malzahn in Bhatia's lab; and Erkki Ruoslahti, professor at the University of California, Santa Barbara all contributed to this work.

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Journal reference:

1. Park et al. Biodegradable luminescent porous silicon nanoparticles for in vivo applications. Nature Materials, 2009; DOI: 10.1038/nmat2398